Amides can be reduced to amines if reacted with lithium aluminum hydride (a strong reducing agent, such as lithium aluminum hydride). 2
Cross-coupling reactions catalysed by palladium pincer complexes. ) complexes containing ancillary and modular poly-pyridine ligands.
A promising class of luminescent derivatives of Silver(I) and Gold(I)‐
Aviel Anaby, Burkhard Butschke, Yehoshoa Ben-David, Linda J. W. Shimon, Gregory Leitus, Moran Feller, and David Milstein . Number of times cited according to CrossRef: Shannon Stahl Is the Winner of the 2020 Probing the effect of heterocycle-bonding in PNX-type ruthenium pre-catalysts for reactions involving H
Autotandem Aromatization–Dearomatization Pathways for PNP-RuII-Catalyzed Formation of Imine and Hydrogen from Alcohol and Amine.
Leonid Schwartsburd, Mark A. Subhas Samanta, Serhiy Demesko, Sebastian Dechert, Franc Meyer. Selective Iron-Catalyzed Deaminative Hydrogenation of Amides.
Stepwise Metal-Ligand Cooperation by a Reversible Aromatization/Deconjugation Sequence in Ruthenium Complexes with a Tetradentate Phenanthroline-Based Ligand. Transformation of CO2 to Methanol with Homogeneous Catalysts.
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When iron met phosphines: a happy marriage for reduction catalysis. Ruthenium complexes bearing an unsymmetrical pincer ligand with a 2-hydroxypyridylmethylene fragment: active catalysts for transfer hydrogenation of ketones. Jacorien Coetzee, Haresh G. Manyar, Christopher Hardacre, David J. Cole-Hamilton. Tell your doctor and pharmacist about all of your drugs (prescription or OTC, natural products, vitamins) and health problems. If you do not receive an email within 10 minutes, your email address may not be registered, Matthias Vogt, Orestes Rivada-Wheelaghan, Mark A. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. Niacinamide side effects (in more detail). Priyanka Choudhary, Ashish Bahuguna, Ajay Kumar, Sandeep Singh Dhankhar, C. M. Nagaraja, Venkata Krishnan. Biswajit Saha, Gargi Sengupta, Abir Sarbajna, Indranil Dutta, Jitendra K. Bera. without permission from the American Chemical Society. Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane. Monica Trincado, Dipshikha Banerjee, Hansjörg Grützmacher.
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Metal–Ligand Bifunctional Catalysis: The “Accepted” Mechanism, the Issue of Concertedness, and the Function of the Ligand in Catalytic Cycles Involving Hydrogen Atoms.
Aldehyde Binding through Reversible C–C Coupling with the Pincer Ligand upon Alcohol Dehydrogenation by a PNP–Ruthenium Catalyst. Design and Syntheses of Palladium Complexes of NNN/CNN Pincer Ligands: Catalyst for Cross Dehydrogenative Coupling Reaction of Heteroarenes. Moran Feller, Eyal Ben-Ari, Yael Diskin-Posner, David Milstein. Computational Insight into the Mechanism of Selective Imine Formation from Alcohol and Amine Catalyzed by the Ruthenium(II)-PNP Pincer Complex. Experimental procedures and X-ray data for complex 4 in CIF format. Boopathy Gnanaprakasam, Ekambaram Balaraman, Chidambaram Gunanathan, David Milstein. Selective hydrogenation of primary amides and cyclic di-peptides under Ru-catalysis. Bottom-Up Construction of a CO2-Based Cycle for the Photocarbonylation of Benzene, Promoted by a Rhodium(I) Pincer Complex. It also serves as an alternative way to navigate the website, and as a means of coming up with retrosynthetic ideas. P-rhodium(
This can be a useful alternative when substrates have functional groups that are incompatible with LiAlH4 or BH3.
Maniklal Shee.
Qinyue Deng, Yajing Shen, Haibo Zhu, Tao Tu. Ekambaram Balaraman, Eugene Khaskin, Gregory Leitus, David Milstein. Sellappan Selvamurugan, Rangasamy Ramachandran, Govindan Prakash, Muthukumaran Nirmala, Periasamy Viswanathamurthi, Shoji Fujiwara, Akira Endo.
Anionic Nickel(II) Complexes with Doubly Deprotonated PNP Pincer-Type Ligands and Their Reactivity toward CO2. Zufar N. Gafurov, Giyjaz E. Bekmukhamedov, Alexey A. Kagilev, Artyom O. Kantyukov, Il’yas F. Sakhapov, Ilya K. Mikhailov, Khasan R. Khayarov, Ruslan B. Zaripov, Daut R. Islamov, Konstantin S. Usachev, Lapo Luconi, Andrea Rossin, Giuliano Giambastiani, Dmitry G. Yakhvarov.
Robert Langer, Ido Fuchs, Matthias Vogt, Ekambaram Balaraman, Yael Diskin-Posner, Linda J. W. Shimon, Yehoshoa Ben-David, David Milstein. Jing Zhang, Ekambaram Balaraman, Gregory Leitus, and David Milstein .
Wen-Hua Zhang, Sheau Wei Chien, T.S.
Nicolas Frank, Katharina Hanau, and Robert Langer .
Siong Wan Foo, Shun Oishi, Susumu Saito. This medicine may affect certain lab tests. Jeremy M. John, Satoshi Takebayashi, Nupur Dabral, Mark Miskolzie, and Steven H. Bergens . ) Zinc-Catalyzed Chemoselective Reduction of Tertiary and Secondary Amides to Amines.
All catalyst components are commercially available, and the reaction proceeds under mild conditions with retention of stereocenters in both reaction partners, while producing only water as a by‐product. Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration. Siwei Shu, Meijie Huang, Jingxing Jiang, Ling-Bo Qu, Yan Liu, Zhuofeng Ke. Rhiann E. Andrew and Adrian B. Chaplin . Available for Android and iOS devices. http://pubs.acs.org/page/copyright/permissions.html. . Sustainable Conversion of Carbon Dioxide: An Integrated Review of Catalysis and Life Cycle Assessment. Shaoqu Xie, Wanli Zhang, Xingying Lan, Hongfei Lin. Reductive Cleavage of Amides to Alcohols and Amines Catalyzed by Well-Defined Bimetallic Molybdenum Complexes. and you may need to create a new Wiley Online Library account. Reversible Formation of Ketimido- and Enamido-Rhenium PNP Pincer Complexes and Relevance to Catalytic Design. Homogeneous cobalt-catalyzed deoxygenative hydrogenation of amides to amines. Transmetallation from CCC-NHC pincer Zr complexes in the synthesis of air-stable CCC-NHC pincer Co(
Acid to Alcohol. Cyclometalated Dicarbonyl Ruthenium Catalysts for Transfer Hydrogenation and Hydrogenation of Carbonyl Compounds. Deaminative and Decarboxylative Catalytic Alkylation of Amino Acids with Ketones. H
Coordination Versatility of sp3-Hybridized Pincer Ligands toward Ligand–Metal Cooperative Catalysis. Acceptorless dehydrogenative coupling with Ru-based catalysts for the synthesis of
Hydrogenation of Dimethyl Carbonate to Methanol by trans-[Ru(H)2(PNN)(CO)] Catalysts: DFT Evidence for Ion-Pair-Mediated Metathesis Paths for C–OMe Bond Cleavage. Ekambaram Balaraman, Yehoshoa Ben-David, David Milstein. Faraj Hasanayn, Abdulkader Baroudi, Ashfaq A. Bengali, and Alan S. Goldman .
Catalytic hydrogenation of tertiary amides at low temperatures and pressures using bimetallic Pt/Re-based catalysts. Metal–Ligand Cooperation in Cyclometalation and Catalysis. Organometallic Complexes of Phosphinopyridines and Related Ligands. Synthesis of Titanium Complexes Supported by Carbinolamide- and Amide-Containing Ligands Derived from Ti(NMe Mild and selective hydrogenation of aromatic and aliphatic (di)nitriles with a well-defined iron pincer complex. Jai Anand Garg, Subrata Chakraborty, Yehoshoa Ben-David, David Milstein. Please check your email for instructions on resetting your password. Lewis Acid-Promoted Heterogeneous Platinum Catalysts for Hydrogenation of Amides to Amines. Ekambaram Balaraman, Eran Fogler, David Milstein. (4) Selectivity studies demonstrated the following order of amide reactivity: 1° >2° >3°. Carboxylic acids are easily reduced by lithium aluminum hydride under mild conditions. Pawan Kumar, Vitthalrao S. Kashid, Yernaidu Reddi, Joel T. Mague, Raghavan B. Sunoj, Maravanji S. Balakrishna. 2
Murugan Subaramanian, Ganesan Sivakumar, Jessin K. Babu, Ekambaram Balaraman. Efficient Catalyst for Acceptorless Alcohol Dehydrogenation: Interplay of Theoretical and Experimental Studies. from the ACS website, either in whole or in part, in either machine-readable form or any other form O
Jason A. Denny, Robert W. Lamb, Sean W. Reilly, Bruno Donnadieu, Charles Edwin Webster, T. Keith Hollis. Yu-Nong Li, Ran Ma, Liang-Nian He, Zhen-Feng Diao. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Ruthenium pincer complexes: Ligand design and complex synthesis. Ru(0) and Ru(II) Nitrosyl Pincer Complexes: Structure, Reactivity, and Catalytic Activity. Ekambaram Balaraman, Chidambaram Gunanathan, Jing Zhang, Linda J. W. Shimon, David Milstein. Synthesis, Characterization and Catalytic Application of Pyridine-Bridged N-Heterocyclic Carbene-Ruthenium Complexes in the Hydrogenation of Carbonates. Kevin Farrell, Philipp Melle, Robert A. Gossage, Helge Müller-Bunz, Martin Albrecht. If you think there has been an overdose, call your poison control center or get medical care right away. Role of a Noninnocent Pincer Ligand in the Activation of CO2 at (PNN)Ru(H)(CO). Nuria Ortega, Christian Richter, and Frank Glorius . N–H Activation by Rh(I) via Metal–Ligand Cooperation. Thompson.
catalysed chemoselective hydrosilylation of α,β-unsaturated amides for the formation of allylamines. Mechanism of SmI2/Amine/H2O-Promoted Chemoselective Reductions of Carboxylic Acid Derivatives (Esters, Acids, and Amides) to Alcohols. The separation of phosphine oxide impurities can be difficult. iii
Unlimited viewing of the article PDF and any associated supplements and figures. Conversion of chitin derived N-acetyl-
Homogeneous Catalytic Hydrogenation of Amides to Amines. breath that smells like fruit. Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset. Metal–Ligand Cooperation in H2 Activation with Iron Complexes Bearing Hemilabile Bis(diphenylphosphino)amine Ligands. 1) Smith, M. B.; March's Advanced Organic Chemistry, 7th Edition, 2) Caron, S.; Practical Synthetic Organic Chemistry, 3) Burke, S. D.; Danheiser, R. L.; Handbook of Reagents for Organic Synthesis, Oxidizing and Reducing Agents, 4) Anderson, N. G.; Practical Process Research and Development, a Guide for Organic Chemists, 2nd Edition. Ruthenium PNN(O) Complexes: Cooperative Reactivity and Application as Catalysts for Acceptorless Dehydrogenative Coupling Reactions. Nicole L. Lampland, Megan Hovey, Debabrata Mukherjee, and Aaron D. Sadow . the alcohol products in very high yields. Shuanming Zhang, Salvatore Baldino, and Walter Baratta . Organophotoredox‐Mediated Amide Synthesis by Coupling Alcohol and Amine through Aerobic Oxidation of Alcohol. ligand-cooperation mediated by iridium pincer complexes. Synthesis and characterization of five-coordinate, 16-electron Ru
Information about how to use the RightsLink permission system can be found at These metrics are regularly updated to reflect usage leading up to the last few days. A primary amine reacts with an anhydride to give an N‐substituted amide. Polynuclear lanthanide–diketonato clusters for the catalytic hydroboration of carboxamides and esters. Jing Zhang, Bin Guo, David James Young, Hong-Xi Li.
Kisan, Valerio Bertolasi, AnvarhuseinA. Steven Giboulot, Salvatore Baldino, Maurizio Ballico, Hans Günter Nedden, Daniele Zuccaccia. A New Pathway for Carbonyl Hydrogenation. Yinjun Xie, Yehoshoa Ben-David, Linda J. W. Shimon, and David Milstein . and you may need to create a new Wiley Online Library account. CO
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Recent Literature A simple ruthenium catalyst mediates a direct coupling between an alcohol and an amine with the liberation of two molecules of dihydrogen. Lluís Artús Suàrez, Zuzana Culakova, David Balcells, Wesley H. Bernskoetter, Odile Eisenstein, Karen I. Goldberg, Nilay Hazari, Mats Tilset.
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